偏高岭土对高性能水泥砂浆性能的影响

研究了偏高岭土的火山灰活性,考察了不同偏高岭土掺量对高性能水泥砂浆的流动度、抗折强度、抗压强度和氯离子渗透性的影响.试验结果表明:偏高岭土的火山灰活性高于硅灰;偏高岭土颗粒形貌的不规则性会降低新拌砂浆的流动度;偏高岭土的掺入使砂浆的抗折强度降低,90d养护龄期时偏高岭土掺量为10%的砂浆抗折强度高于偏高岭土掺量为6%,14%的砂浆抗折强度.偏高岭土掺量为10%的砂浆的后期抗压强度最高,90 d养护龄期时可达96.3 MPa;56 d龄期时偏高岭土掺量为0%,6%,10%,14%的砂浆的氯离子渗透性都较低,电通量分别为165,221,191,158 C.     

冷却速率和奥氏体化温度对40 Cr钢球化退火的影响

为探究奥氏体化温度和冷却速率对40Cr钢球化过程的影响,采用双相区球化退火研究了热轧态40Cr钢的球化退火行为和力学性能。奥氏体化温度从760℃提高到800℃,冷却速率从10℃·h-1上升到30℃·h-1,组织硬度随冷却速度呈V形变化,碳化物球化率随冷却速度变化正好与前者相反。奥氏体化温度为760℃,冷却速率为20℃·h-1所得到的球化组织球化率高,且碳化物细小,具有良好的冷成形性能,可大幅度缩短球化退火时间,显著提高生产效率。提出了球化退火过程中离异共析转变机制,控制好球化过程中奥氏体化温度、冷却速率及保温时间有利于离异共析转变的发生。     

氧含量对Ti-35Nb-3.7Zr-1.3Mo-xO合金组织与力学性能的影响

根据d电子设计理论设计了新型亚稳β合金Ti-35Nb-3.7Zr-1.3Mo-x O,研究了氧含量对该合金组织与力学性能的影响.实验结果表明,合金经固溶后主要为β相,其晶粒尺寸随氧含量提高而细化.低氧合金中存在少量α″相,氧元素对水淬α″相的形成具有抑制作用.冷轧后组织仍主要为β相,但因大变形后缺陷增多而结晶度降低.不同氧含量的合金冷轧后分别出现细针α″相、板条状ω相、锯齿孪晶以及应力诱发α″相等特殊组织.冷轧态Ti-35Nb-3.7Zr-1.3Mo-x O合金的抗拉强度、弹性模量和硬度均随氧含量的提高而升高,但塑性变差.氧含量升高0.1%,则抗拉强度增加约100 MPa;氧含量升高0.3%,则维氏硬度升高约为50;弹性模量处于45~75 GPa之间.在氧含量超过0.6%以后,合金塑性明显变差.     

Structure and magnetic properties of Ni50Mn35In15 thin film

Thin film of Ni50Mn35In15 Heusler alloy was prepared on Mg O(001) substrate by epitaxial growth in an ultra-high vacuum(UHV) chamber by a Pulsed Laser Deposition(PLD) method. The epitaxial growth process was monitored by in situ reflection high energy electron diffraction(RHEED) and the structure of the film was checked by ex situ X-ray diffraction(XRD), which indicates that high quality Ni50Mn35In15 single crystal film with a face-centered-cubic(fcc) structure could be stabilized on Mg O(001). Magnetic property measurement was also conducted at various temperatures by using physical property measurement system(PPMS). A significant exchange bias was observed for Ni50Mn35In15 film,and the strength of the exchange bias field(HEB) increases with the decrease of temperature. Such a behavior can be ascribed to the fact that the interfacial spin interaction between ferromagnetic(FM) and antiferromagnetic(AFM) cluster is enhanced with the decrease of temperature.     

Improving thermal insulation of TC4 using YSZ-based coating and SiO2 aerogel

In this paper, air plasmas spray(APS) was used to prepare YSZ and Sc2O3–YSZ(Sc YSZ) coating in order to improve the thermal insulation ability of TC4 alloy. Si O2 aerogel was also synthesized and affixed on TC4 titanium alloy to inhabit thermal flow. The microstructures, phase compositions and thermal insulation performance of three coatings were analyzed in detail. The results of thermal diffusivity test by a laser flash method showed that the thermal diffusivities of YSZ, Sc2O3–YSZ and Si O2 aerogel are 0.553, 0.539 and 0.2097 10 6m2/s, respectively. Then,the thermal insulation performances of three kinds of coating were investigated from 20 1C to 400 1C using high infrared radiation heat flux technology. The experimental results indicated that the corresponding temperature difference between the top TC4 alloy(400 1C) and the bottom surface of YSZ is 41.5 1C for 0.6 mm thickness coating. For 1 mm thickness coating, the corresponding temperature difference between the top TC4 alloys(400 1C) and the bottom surface of YSZ, Sc YSZ, Si O2 aerogel three specimens is 54, 54.6 and 208 1C, respectively. The coating thickness and species were found to influence the heat insulation ability. In these materials, YSZ and Sc YSZ exhibited a little difference for heat insulation behavior. However, Si O2 aerogel was the best one among them and it can be taken as protection material on TC4 alloys. In outer space,Si O2 aerogel can meet the need of thermal insulation of TC4 of high-speed aircraft.     

Effect of equal channel angular pressing on aging treatment of Al-7075 alloy

The effect of aging treatment on microstructure and mechanical properties of equal channel angular pressed Al-7075 alloy was examined.Commercial Al-7075 alloy in the solid solution heat-treated condition was processed by equal channel angular pressing through route BCat both the room temperature and 120 1C. Only three passes of equal channel angular pressing was possible due to the low ductility of the alloy at both temperatures. Followed by equal channel angular pressing, the specimens have been aged at 120 1C for different aging times. Mechanical properties were measured by Vickers microhardness and tensile tests and microstructural observations were undertaken using transmission electron microscopy, X-ray diffractometer as well as optical microscopy. Microstructural investigations showed that ultrafine-grained materials with grain size in the range of 200–350 nm and 300–500 nm could be obtained after three passes of equal channel angular pressing at room temperature and 120 1C, respectively. Equal channel angular pressing of solid solution heat-treated Al-7075 alloy accelerates precipitation rate and subsequently leads to a significant decrease in aging time to attain maximum mechanical properties. Furthermore, it is possible to achieve maximum mechanical properties during equal channel angular pressing at 120 1C as a result of dynamic aging and formation of small η′ phase.     

Influence of thermal-decomposition temperatures on structures and properties of V2O5 as cathode materials for lithium ion battery

Submicron spherical V2O5 particles with a uniform size and a lower crystallinity were successfully synthesized by a chemical precipitationthermal decomposition technique using the commercial V2O5 powders as starting material. The crystal structure and grain morphology of samples were characterized by X-ray diffraction(XRD) and scanning electron microscopy(SEM), respectively. Electrochemical testing such as discharge–charge cycling(CD) and cyclic voltammetry(CV) were employed in evaluating their electrochemical properties as cathode materials for lithium ion battery. Results reveal that the crystallinity and crystalline size of V2O5 particles increased when the thermal-decomposition temperature increased from 400 ℃ to 500 ℃, and their adhesiveness was also synchronously increased. This indicate that the thermaldecomposition temperature palyed a significant influence on electrochemical properties of V2O5 cathodes. The V2O5 sample obtained at 400 ℃ delivered not only a high initial discharge capacity of 330 m A h g-1and also the good cycle stability during 50 cycles due to its higher values ofα in crystal structure and better dispersity in grain morphology.     

桥式起重机吊钩横梁的疲劳寿命估算

以某库房32 t桥式起重机的吊钩横梁为研究对象,通过有限元分析和现场实测确定吊钩横梁危险部位应力与起重量的关系;并通过监测起重机的工作循环次数和起重量获取吊钩横梁危险部位的应力谱.在此基础上,结合材料的P-S-N曲线,利用线性累积损伤理论对吊钩横梁进行了疲劳寿命估算.     

苏里格气田东部致密砂岩储层的沉积-成岩约束

鄂尔多斯盆地苏里格气田是我国陆上产能最大的气田,而储层低孔低渗的特点是制约该气田开发的关键因素。为了探讨砂岩储层低孔低渗的成因机理和主控因素,在岩心观察、薄片鉴定、流体包裹体分析、X-射线衍射、阴极发光分析、扫描电镜分析等基础上,进行了系统的沉积微相和成岩作用研究。研究表明,主要产气层山1、盒8段砂体形成于辫状河心滩、辫状河道及曲流河边滩等水动力条件强的沉积微相;成岩作用无疑是砂岩储层物性变差的主要原因;但沉积微相奠定了岩石结构和沉积期后作用的物质基础,对成岩作用和储集性能产生重要影响。     

金塔盆地与鼎新谷地地质接触关系及其地电特征研究

金塔盆地与鼎新谷地之间的地质接触关系,至今为止还没有系统的研究。金塔盆地与鼎新谷地之间的水力联系一直不能做出正确判断。在分析区域资料的基础上,进行了研究区地质调查,并在国内首次开展了该问题的地电研究工作,对比了地质接触关系与地电特征的符合程度,并进一步分析了金塔盆地与鼎新谷地的地质接触关系和水力联系。地电特征研究结果显示金塔盆地和鼎新谷地地质接触关系及其地电特征存在明显的一一对应关系。结论认为黑河干流下部存在古近系砂砾岩、砂岩和泥质粉砂岩基底隆起及其伴随断层,该基底隆起和伴随断层构成了金塔盆地和鼎新谷地之间的地质接触关系,并且阻碍了两者之间的地下水水力联系。研究工作为黑河下游地下水水资源量评价、区域生态环境治理和恢复提供了科学的依据。